8–44.0 1992.1924 Ac Aib Ala Aib Aib Aib Gln Aib Aib Aib Ala Lxx Vxx Pro Vxx Aib Vxx Gln Gln Tyr(C 5 H 8 )ol 49 44.6–44.7 1979.1585 Ac Aib Ala Ala Aib Aib Gln Aib Aib Aib Ala Lxx Vxx Pro Vxx Aib Vxx Gln Glu Tyr(C 5 H 8 )ol 50 45.0–45.1 1993.1762 Ac Aib Ala Aib Aib Aib Gln Aib Aib Aib Ala Lxx Vxx Pro Vxx Aib Vxx Gln Glu Tyr(C 5 H 8 )ol 51 45.9–46.1 2007.1881 Ac Vxx Ala Aib Aib Aib Gln Aib

Aib Aib Ala Lxx Vxx Pro Vxx Aib Vxx Gln Glu Tyr(C 5 H 8 )ol No. Compound identical or positionally isomeric with Ref.                                         35 Voglmayrin-1 (N-terminal heptapeptide, pos. Nec-1s price 13–15 and 18 cf. trichokonin V) Huang et al. 1995                                       36 Voglmayrin-2 (cf. 35: [Ala]4 → [Aib]4, [Glu]17 → [Gln]17: deletion sequence of SU5402 concentration 37)                                           37 Voglmayrin-3 (cf. 36: + C-terminal Tyrol)                                      

    38 Voglmayrin-4                                           39 Voglmayrin-5 (cf. 37: [Gln]18 → [Glu]18)                                           40 Voglmayrin-6 (N-terminal nonapeptide cf. trichorzianine B-VIb, [Ser]10 → [Ala]10, C-terminal nonapeptide cf. trichorzianine B-VIb, [Ile]16 → [Vxx]16) Rebuffat et al. 1989                                       41 Voglmayrin-7                                           42 Voglmayrin-8 (homologue of 40: [Gln]18 → [Glu]18)                                           43 Voglmayrin-9 (homologue of 40: [Aib]12 → [Vxx]12)                                           44 Voglmayrin-10 (homologue of 37: [Tyrol]19 → [Pheol]19)                                           45 Voglmayrin-11 (homologue of 39: [Tyrol]19 → [Pheol]19)                              

            46 Voglmayrin-12                                           47 Voglmayrin-13 (homologue of 48: [Aib]3 → [Ala]3)                                           48 Voglmayrin-14 (homologue of 37 and 44: prenylated [Tyrol]19)                                           49 Voglmayrin-15 (homologue of 38: prenylated [Tyrol]19)                                           50 Voglmayrin-16 (homologue Astemizole of 49: [Ala]3 → [Aib]3)                                           51 Voglmayrin-17 (homologue of 50: [Aib]1 → [Vxx]1)                                           aVariable residues are underlined in the table header. Minor sequence variants are underlined in the sequences. This applies to all sequence tables bC5H8, prenyl (Prn) or https://www.selleckchem.com/products/sotrastaurin-aeb071.html isoprenyl residue at OH-group of Tyr postulated. For details, see text Table 9 Sequences of 11- and 19-residue peptaibiotics detected in the plate culture of Hypocrea voglmayrii No. tR [min] [M + H]+   Residuea 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 52 35.2–35.6 1852.0739 Ac Aib Ala Ala Aib Aib Gln Ala Aib Aib Ala Lxx Aib Pro Vxx Aib Aib Gln Gln Pheol 53 35.6–35.8 1866.0884 Ac Aib Ala Ala Aib Aib Gln Ala Aib Aib Ala Lxx Aib Pro Vxx Aib Vxx Gln Gln Pheol 40 37.3–37.6 1880.